There are several tax breaks for college tuition payments: an above-the-line deduction (this break expired at the end of 2013 but likely will be extended for 2014), education tax credits, an exclusion for interest on U.S. savings bonds that you redeem, and penalty-free withdrawals from IRAs. At tax time, review all of the available options (there are different income limits and other rules to consider) before making a choice of which break to use.
For 2007, a high deductible health plan is a health plan with an annual deductible that is not less than $1,100 for self-only coverage or $2,200 for family coverage, and with annual out-of-pocket expenses that do not exceed $5,600 or $11,200, respectively.